## Cathodic Protection

### By Roger Alexander

#### Corrosion Technologist

In order to appreciate the limitations of traditional techniques of using a voltmeter and earth contact in cathodic protection and corrosion control monitoring, it is necessary to examine the basic axioms upon which established theory is based.

Cathodic protection specialists would have us believe that there is something special about cathodic protection that sets it aside from normal electrical measurement. However the instruments that are used are electrical meters which are only capable of making the same measurements as any other electrical meters.

## The Meter

Whatever system of metering is used, it will ultimately only indicate the voltage between the two terminals on the meter.

Null-balancing, high internal resistance, digital/analogue electronics and all other refinements of present-day technology do not make the meter capable of doing anything more than measuring the voltage between the potentials at the meter end of the conductive test leads.

The voltage on the meter is therefore the Potential Difference (PD) at the test lead contact points.

## What are we measuring?

A voltage is the difference between two potentials, and a potential is an electric property. All materials are electrically conductive, but the degree of conductivity or resistance has an effect on the passage of electrical current. Some materials have such a high resistance as to be disregarded as conductors in the circuits we shall be discussing, while others have such a low resistance that they can be regarded as electrically homogeneous. The materials in between these extremes can be studied to reveal the behaviour of the voltmeter under different electrical conditions at the contact points.
Here's an experiment that shows one such use of the voltmeter
Take an insulated trough of damp sand and a 9-v dry cell, with the terminals connected to either end of the damp sand. Place the voltmenter conductors at various locations along the sand trough and observe the readings. It will be found that a variety of readings between 0 and 9v will be displayed on the meter, dependent on the position of the voltmeter probes.
Observation
The sand can be divided into zones of electrical potentials and it is the differences between these zones which results in the voltage displayed

## Electricity in the ground.

The concept of potential zones can be considered in two dimensions by repeating the experiment using an insulating tray, instead of a trough, full of damp sand, as shown in the drawing. With one voltmeter probe placed in a fixed position, it is possible to scribe in the sand 'isobars' of constant voltage round each of the battery contact points. These lines will define the boundaries of the zones of similar potential. No voltage will be shown on the meter when both of the probes are placed on one of these lines even though the probes are in different positions along the line. The lines form 'contours' of the potential shape within the tray.

It will be noted that the shape of these contours can be altered by altering the conductivity of the sand by adding salt solution and the shapes are only predictable when the sand is of uniform conductivity.
It is possible to make an electrical model of the electric components further to demonstrate the complexities involved in DC electrical fields of this nature. If two chains of resistors link two different potentials and the value of each resistor is different, then we can see the variations in voltage between the two nodes is equal to the square of the number of resistors. If a grid of resistors is constructed with random values and the probes of the voltmeter placed at various locations, it would require a computer to predict the results.

Put a third dimension onto the grid, and the computer would have to be fed with every resistance value in order to predict the voltage resulting from the probes placed at surface nodes. Two or more resistances of unspecified value included in the system would make the result impossible to predict with any computer. (It is,of course, true that given the same source, the voltage between any two nodes would be constant.)The illustration below shows the results of an actual field survey and demonstrates the complexitites of normal field conditions.

# Integrity of corrosion-control monitoring

We can use the following experiment to test the integrity of imagining an 'electrical picture' caused by varying ground potentials.
Choose a buried cathodicaly-protected pipeline running though areas of soil of different resistances.

Place a metal coupon in a high-resistance soil and another in a low-resistance soil, both connected to the same pipeline.

Using a high-resistance voltmeter and two probes, plot the potentials surrounding the coupons in the same way as was done in the sand tray.

In the case of the high-resistance soil, the potential gradient will spread much further than that of the coupon in the low-resistance soil.

Observation

The area of influence of the coupon can vary from a few millimeters in low-resistance soils to many meters in extremely-high resistant circumstances such as fresh water, sand and gravel.

The recognition of this fact is important in the understanding of such survey techniques as the two half cell survey (which is now known as DCVG).

## Measuring the effects of current from a corrosion reaction

The above illustration shows the effect of various depths of cover on the voltages between the meter probes in the circumstances where corrosion on a pipeline at a coating fault location is causing a potential difference to exist between a cothodic and an anodic pipe-to-soil interface. It can be seen that the exact depth of cover and all the soil resistances between the probe and the pipe/soil interface must be known to calculate the interface potential.

This is readily demonstrated where an excavation is dug over a coating fault on a cathodically-protected pipeline. Using 2 half-cells across a voltmeter(as probes) it is possible to plot the potential zones as the work progresses towards the coating fault. It is found that these zones vary in shape according to the conductivity of the backfill.

In high-resistant soils, the zones break the surface but in some low-resistance soils they do not. It is for this reason that the 'close- interval potential survey' is not reliable for finding coating defects.

It is now appropriate to consider the half-cell in the measuring circuit. Similar illustrations to the one below can be found in various publications, thus acknowledging the fact that it is possible to measure a different voltages between the same half-cells when they are placed in different contact positions with the ground or water in which the pipeline is submerged. The author has developed several successful field survey techniques based on this fact.

The recognition of the variablility of the voltages obtainable between two half-cells should be sufficient in itself to indicate that neither half-cell can be regarded as a reference potential which could be used as a fixed electrical value against which to plot a survey graph of pipe-to -soil potential. However, the half-cell, used as an earth contact probe, does overcome the problems of introducing a metal/environment reaction into the circuit and is therefore a useful tool.
The extent to which half-cell to half-cell voltages can vary can be dramically demonstrated by plotting the potential gradients around a groundbed of an impressed-current cathodic protection system.
With one half-cell placed over the pipeline but at least 100m remote (from the groundbed ), the other half-cell is stepped over the groundbed.
A typical plot, like the one below, is shown, where a difference of over 8v is measured between one 'reference' electrode and the other. T
he polarity of the connections to the meter does not alter the value of the voltage shown (provided the meter is digital or centre-null) and the movement of either half-cell produces a changing reading when it is placed in a zone of different potential.

This raises the question How can the half-cell be regarded as a reference when the voltage shown between the two half-cells is not consistent when used in this way?

It is common practice to connect one side of the voltmeter to the pipeline, or other structure to be surveyed, using a metal conductor and the other side to the copper in a CuSO4 half-cell. The half-cell is then put in contact with the ground and a voltage shows on the meter. It is shown below, that this voltage that the voltage will increase as the half-cell is moved towards the center of a CP groundbed area.

The connection to the pipe remains unaltered and the only change in the circuit is the location of the half-cell. This will increase the voltage shown to almost the transformer-rectifier voltage when the half-cell is close to the anode. It is the potential on the half-cell side of the meter which has increased, for the other side of the meter is untouched.
If a coating fault exists, then the voltage will decrease as the half-cell is moved towards the fault, as explained above in relation to the use of two half-cells. The pipe is the 'reference' against which the ground potentials are measured in this type of survey.

## Ground Potential Alteration

During a voltage survey between a pipe and a 'roving' half-cell, the ground potentials can be altered by the presenceof a bi-metallic coupling buried under the half-contact point.
As the half-cell is moved over the anodic part of this coupling it is in contact with a zone of higher potential and the voltage on the meter will increase.
Similarly, when it moves over the cathodic part of the coupling the voltage will decrease.
It does not matter that the potential zones are caused by an electromotive force which is indepentent of the pipeline being monitored.

Using an insulated tray of damp sand and a short length of steel pipe, illustrated below, it is possible to make a model which will clearly demonstrate this misleading effect.

A bi-metallic coupling is set up between a piece of magnesium and a copper rod buried in the sand, and the pipe-soil potentials are taken in the traditional way using a high-resistance voltmeter between the pipe and the half-cell.
By moving the half-cell contact point to different points in the tray it is possible to obtain readings between 0.005v and 1.3v.

The pipe is not in metallic contact with the magnesium or copper, but must not be completely insulated in order that it should make contact with the damp sand. (This is to allow the measuring circuit to be completed, as it would be through imperfections in the pipe coating in field conditions.)

Using this model it is seen that a voltage can be measured between two potential fields even though they are not interfering with one another.

This experiment can be repeated using an actual pipeline in the field and placing a bi-metallic coupling in the ground.

Pipe-to-soil readings can be altered by as much as 0.8v by placing the half-cell in various positions in the electrical field of the coupling.

In one over-the-line potential survey a potential depression was excavated at a fault location signal identified originally on a Pearson-type survey. The cause was found to be a steel wellpoint pipe which has been abandoned after construction of the pipeline. The wellpoint pipe had a galvanized fitting which caused the electrical potential ground distrubance, but no contact with the steel pipe existed. The pipe coating and metal condition were perfect at this location.

On a cathodically-protected pipeline a coating fault will provide an area of low-resistance whereby the TR(Transformer-Rectifier) current can pass onto the metal pipe. This creates a field of varying potential zones around the coating fault, and the placing of the half-cell within these zones will affect the voltage shown on the meter. If the bi-metallic coupling is placed with its anodic interface over the coating fault, the effect would be to 'mask' the meter from the pipeline's influence, and the fault would go undetected. This can be demonstrated in the field.

At a cathodic protection test connection, we can create an artificial coating fault by placing a steel coupon in the ground and conncecting it to the pipeline. The potential zones around the coupon can be plotted in the ground. If the soil resistance at the test site is sufficient, the zones of influence will extend over 1m from the coupon. We can then draw a straight line through the area, the same distance from the coupon as the depth of the cover to the pipe. By moving the half cell along this line we can acheive a plot readings similar to that which would be obtainable in conducting an over-the-line type pipe-to-soil potential survey. We have in fact created a 'section' of such a survey flat on the ground. Using a bi-metallic coupling we can produce an independent electrical field which mask the voltage shift caused on the meter by the presence of the coupon. It can be easily arranged that the current flowing into the coupon is not distrubed, thus demostrating that traditional voltage readings can be misleading.
In the light of this result, we should re-consider our concept of 'interference' from other CP systems. The field caused by a groundbed or a coating fault on a 'protected' foreign service need not cause any damage to our own plant, even if massive voltage changes are shown during 'interference testing', the ground potential swings of several volts need not result in current flowing onto or from the pipes. In other more dangerous circumstances, however, current can be flowing from a pipe without the effects being detectable at the ground surface.
Further alterations to the voltages on the meter can be caused by the resistance of the layers in the environment between the pipeline metal and the point of contact of the probe or half-cell, in the diagram below. These varying resistances alter the shape of the zones of potential and the position of the half-cell can alter the reading obtained. The feature had been overcome in recent years by the introduction of digital meters which draw very little current, but it is still very noticeable in arid climates and over surfaces such as tarmac and concrete.

It can be seen that the potential on the half-cell side, of the meter can be shifted by electrical fields in the ground at the point of contact of the half-cell. Over the past ten years, the author has witnessed the voltage shifts shown in the following table:

Pipeline Diameter And Location(ins) Coating Fault Shift(v) Undefined Shift(v) Total Known Error(v)
30 - rural -0.200 -0.600 -0.800
24 - rural -0.100 -0.400 -0.500
24 - rural 0 -0.150 -0.150
24 - gas works 0 -0.400 -0.400

During investigations at other sites, scrap batteries, buried tools, welding rods, farm implements and parts, abandoned 'foreign' services, abandoned concrete bases, disused tips both officical and unofficial, and natural unidentified features have all been found to affect ground potentials by shifts of up to 1.0v.
To complete the half-cell side near the meter, it can be demonstrated that the use of a vehicle's mobile radio transmitter can affect the ground potenial by up to .5v at up to 100m distance, and poorly-earthed AC generators can cause ground potential fluctuations of 0.200v or more. Other sources of fluctuations on this side of the meter can be identified giving totals of over 1v in many locations. The pipeline metal potenial itself may be caused to fluctuate by outside influences causing further confusion to the interpretation of results. Indeed, there is no way of telling which side of the meter is fluctuating using the pipe-meter-half-cell measuring technique.

Connection Of The Meter To The Pipeline
We must now consider the side of the meter which is connected to the metal of the pipeline or structure. It is often conveniently ignored that we make a connection to a single location and that this point is in low-resistance contact with all the interfaces between the environment and the structure/pipeline under test. If we examine a very small pipeline with a very good coating, and there is only one fault/contact, then the potential on this side of the meter is the pipe/soil potential at that fault. If we have more than one fault in the coating it is unlikely that the conditions at the metal-to-environment interfaces will be identical. The potential at each interface will be different and a current will flow between them. This side of the meter is connected to the metal of all the faults, and will be at an average potential resulting from the activity of them all.
Where there is corrosive activity or a difference in metals, we can regard this side of the meter as being connected to many potentials in parrallel. It is impossible to identify the value of any one of these potentials from the single reading on the meter.
An experiment is not necessary to demostrate this fact, as all field-experienced personnel who have worked with sacrificial anode systems can verify the readings obtained. A voltage can be obtained between the pipe-to-soil potential and the half-cell side of the meter. This will be less than the voltage read between the anode and the half-cell side of the meter. When the anode is connected to the pipe and the pipe-to-soil potential is compared to the half-cell side of the meter, the reading will be an average of the two previous readings. The potentials of the pipe metal-to-soil interface and the anode-to-soil interface combine to give a joint potential on this side of the meter.
In a normal field situation, there would be many hundreds of interfaces of differing potentials combining to produce a joint 'natural' potential to the metallic unit which is connected to one side of the meter. It is impossible to identify the value of any one of these without disconnecting it from the others (as we can do with the sacrificial anode). An experiment can be set up to demostrate that corrosion can occur on a steel surface even though the average potential of the metallic body has been reduced to -1.00v with reference to a Cu/CuSo4 half-cell. This experiment can only be set up using the Alexander Cell, and will be described below.
In summary, it can now be stated that the potentials on each side of the meter can vary by ±0.500v, and that most of the causes of these variations have no effect on the corrosive activity on the surface of the pipeline or structure being examined. Conditions have been experienced where the current from a CP system was flowing onto a magnesium anode (thus protecting it) when the pipe-meter-half-cell voltage was less than -0.650v. When the anode was disconnected, the reading decreased to -0.575v and the steel pipeline was in perfect condition despite very poor coating and an active local environment.
When attempting to interpret readings obtained by the pipe-to-soil potential method using a half-cell, we must therefore know :

1. the exact depth of cover and location of the pipe in relation to the half-cell point of contact;
2. the exact resistance of the environment in which the probe is placed;
3. the exact surface area and location of any coating faults;
4. the presence and exact location of any sources of DC electric fields such as scrap, etc.;
5. the pH of the environment at its interface with the metal at each coating fault;
Also, it is important that:
6. ground and pipe flucuations are elimated by using recording voltmeters or data-logging computers; and
7. we would then need a real reference potenital for each pipeline to establish a base line for the potential plot.

Only by using these steps can a criterion be fixed to ensure that corrosionis stopped by cathodic protection, and it can be seen that most of the steps are commonly ignored and others of them are impossible to apply in the field practice of monitoring corrosion control. We can thus see that using a half-cell is similar to using a balance scales(the voltmeter) to assess the weight on one side by placing a known and an unknown weight on the other. Indeed, we even try to do this when the whole assembly is in motion(fluctuation).

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